Wang Jiaxiang (1949.10 - 1951.02)

Zhang Wentian (1951.04 - 1955.01)

Liu Xiao (1955.02 - 1962.10)

Pan Zili (1962.12 - 1966.05)

Liu Xinquan (1970.11 - 1976.03)

Wang Youping (1977.08 - 1979.07)

Yang Shouzheng (1980.04 - 1985.01)

Li Zewang (1985.03 - 1987.07)

Yu Hongliang (1988.09 - 1991.11)

Wang Jinqing (1991.12 - 1995.06)

(Appointed Ambassador to the Russian Federation in February,1992, after the Disintegration of the Soviet Union)

Li fenglin (1995.06 - 1998.09)

Wu Tao (1998.09 - 2001.07)

Zhang Deguang (2001.07 - 2003.10)

Liu Guchang (2003.11 - )