Wu Xiuquan (1955.05-1958.09)
Zeng Tao (1970.08-1973.04)
Zhang Haifeng (1973.08-1978.04)
Zhou Qiuye (1978.07-1981.01)
Peng Guangwei (1981.05-1983.11)
Xie Li (1983.12-1986.11)
Tian Zengpei (1986.06-1988.04)
Ma Xusheng (1988.01-1991.07)
Zhang Dake (1991.03-1993)
(Appointed Ambassador to the Federal Republic of Yugoslavia after the disintegration of the Socialist Federal Republic of)
Zhu Ankang (1992.12-1998.05)
Pan Zhanlin (1997.12-2000.10)
Wen Xigui (2000.04-2003.01)
(Appointed Ambassador to the Serbia and Montenegro after the rename of the former Yugoslavia)
Li Guobang (2003.04- )